HVAC engineers have known for decades the value of desiccants to air conditioning. In fact, one of the pioneers of early A/C, Willis Haviland Carrier, knew of its potential, but opted to go the refrigeration route.
Most people know of desiccants as the pebble-sized handfuls that come with new shoes to keep them dry.
The kind NREL uses are syrupy liquids — highly concentrated aqueous salt solutions of lithium chloride or calcium chloride. They have a high affinity for water vapor, and can thus create very dry air.
Because of the complexity of desiccant cooling systems, they have traditionally only been used in industrial drying processes. Inventing a device simple enough for easy installation and maintenance is what has impaired desiccant cooling from entering into commercial and residential cooling markets.
To solve that problem, the NREL device uses thin membranes that simplify the process of integrating air flow, desiccants, and evaporative cooling. These result in an air conditioning system that provides superior comfort and humidity control.
The membranes in the DEVap A/C are hydrophobic, which means water tends to bead up rather than soak through the membranes. Imagine rain falling on a freshly waxed car. That property allows the membranes to control the liquid flows within the cooling core. "It's that property that keeps the water and the desiccant separated from the air stream," Kozubal said.
"We bring the water and liquid desiccant into DEVap's heat-mass exchanger core," Kozubal said. "The desiccant and evaporative cooling effect work together to create cold-dry air."
http://www.nrel.gov/features/20100611_ac.html